catena-Poly[[chloridocobalt(II)]-μ-5-(8-quinolyloxymethyl)tetrazolato-κ4 N 5,O,N 1:N 4]
نویسندگان
چکیده
In the title compound, [Co(C(11)H(8)N(5)O)Cl](n), the Co(II) atom is penta-coordinated by one O atom and two N atoms from a 5-(8-quinolyloxymeth-yl)tetra-zolate ligand, one N atom from another symmetry-related ligand, and a Cl atom. The coordination geometry can be described as slightly distorted trigonal-bipyramidal. Adjacent Co atoms are connected by the bridging tetra-zole groups into a chain. The dihedral angle between the quinoline and tetra-zole planes is 21.2 (1)°. The structure involves intra- and inter-chain C-H⋯N hydrogen bonds.
منابع مشابه
Poly[(μ2-azido-κ2 N 1:N 1)[μ2-5-(8-quinolyloxymethyl)tetrazolato-κ4 N 1,O,N 5:N 4]manganese(II)]
In the structure of the title compound, [Mn(C(11)H(8)N(5)O)(N(3))](n), the Mn atoms are hexa-coordinated by five N atoms and one O atom. The coordination polyhedron of the Mn atom is a slightly distorted octa-hedron. The Mn atoms are connected by azide anions with a μ(2)-1,1 mode and by 5-(8-quinolyloxymeth-yl)tetra-zolate ligands in a μ(2)-η(1)(N),η(3)-(N,N,O) fashion to form a two-dimensional...
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متن کاملPoly[(μ2-azido-κ2 N 1:N 1)[μ2-5-(8-quinolyloxymethyl)tetrazolato-κ4 N 1,O,N 5:N 4]zinc(II)]
In the title compound, [Zn(C(11)H(8)N(5)O)(N(3))](n), the Zn atom is hexa-coordinated by five N atoms and one O atom in a distorted octa-hedral geometry. The chelating 5-(8-quinolyloxymeth-yl)tetra-zolate ligands are approximately planar, with a dihedral angle of 3.6 (2)° between the quinoline and tetra-zole planes. Adjacent Zn atoms are linked by two bridging azide ligands across a centre of i...
متن کاملcatena-Poly[[bis(pyridine-κN)nickel(II)]-μ-oxalato-κ4 O 1,O 2:O 1′,O 2′]
The title compound, [Ni(C(2)O(4))(C(5)H(5)N)(2)](n), was synthesized under hydro-(solvo)thermal conditions. The Ni(II) atom, lying on a twofold rotation axis, has an octa-hedral coordination geometry involving two N atoms from two pyridine ligands and four O atoms from two oxalate ligands. The Ni atoms are connected by the tetra-dentate bridging oxalate ligands into a one-dimensional zigzag chain.
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عنوان ژورنال:
دوره 64 شماره
صفحات -
تاریخ انتشار 2008